The figure below illustrates the principle of a test method in which the scratch resistance and adhesion of coatings can be measured. The loaded stylus draws on the film surface. It is clear that in a balanced system carrying a stylus there is a simple relationship between the applied load, whose strength can be easily controlled, and the shear force that ultimately causes the coating to fall off. A critical quantity is the radius of the tool tip, which needs to be measured with the same precision as the width of the contact area created during scraping.
Diagram of the scratch technique used to determine the adhesion of polymer films subjected to localized surface forces
It is recommended that the information obtained directly from the test be supplemented with additional data, such as the results of surface profilometers or scanning electron microscopy, which can provide insight into the details of the scratch topography. With such a specification, it is even possible to estimate adhesion values in multilayer systems. It can be seen what type of membrane failure occurs when these systems are subjected to scratch loads.
