What are surface tension, contact angle, hydrophilic and hydrophobic surfaces?

Surface Tension

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 1

Surface tension is a property of liquids caused by unbalanced molecular cohesion at or near the surface, with the result that the surface tends to shrink and behave like a stretched elastic film. Polar liquids exhibit strong surface tension.

Surface tension of various air-liquid interfaces at 293 K (West, RC (Ed.)

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 2

Variation of surface tension at the air-water interface with temperature (West, RC (Ed.).

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 3

Contact angle

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 4

The equilibrium contact angle of a liquid on a rigid surface, measured at the contact line where the three phases (liquid, solid, gas) within the liquid meet.

For example, a water bead on glass has a zero contact angle, but a water bead on an oily surface or plastic may have a contact angle of 90° or greater.

Hydrophilic and Hydrophobic Surfaces

What is surface tension, contact angle, hydrophilic and hydrophobic surfaces?  Picture 5

A substrate surface is said to be hydrophobic when the contact angle with water is greater than 90°. Example Figure A above.

When the contact angle with water is less than 90°, the substrate surface is said to be hydrophilic. Example Figure B above.

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